neighboring$52008$ - traducción al griego
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neighboring$52008$ - traducción al griego

INTRAMOLECULAR INTERACTION
Anchimeric assistance; Neighboring group participation; Neighboring-group participation
  • center

neighboring      
adj. γειτονικός

Definición

Neighborhood
·noun The disposition becoming a neighbor; neighborly kindness or good will.
II. Neighborhood ·noun The quality or condition of being a neighbor; the state of being or dwelling near; proximity.
III. Neighborhood ·noun The inhabitants who live in the vicinity of each other; as, the fire alarmed all the neiborhood.
IV. Neighborhood ·noun A place near; vicinity; adjoining district; a region the inhabitants of which may be counted as neighbors; as, he lives in my neighborhood.

Wikipedia

Neighbouring group participation

In organic chemistry, neighbouring group participation (NGP, also known as anchimeric assistance) has been defined by the International Union of Pure and Applied Chemistry (IUPAC) as the interaction of a reaction centre with a lone pair of electrons in an atom or the electrons present in a pi bond contained within the parent molecule but not conjugated with the reaction centre.[1] When NGP is in operation it is normal for the reaction rate to be increased. It is also possible for the stereochemistry of the reaction to be abnormal (or unexpected) when compared with a normal reaction. While it is possible for neighbouring groups to influence many reactions in organic chemistry (e.g. the reaction of a diene such as 1,3-cyclohexadiene with maleic anhydride normally gives the endo isomer because of a secondary effect {overlap of the carbonyl group π orbitals with the transition state in the Diels-Alder reaction}) this page is limited to neighbouring group effects seen with carbocations and SN2 reactions.